The hysteresis unit system was introduced to mechanical structure behavior of the TiNi SMA joint based on the structure characteristics of the martensite variants in the joints, and some functions reflecting its inner structure characteristics and micro-behavior such as density function, phase transformation function were set up from micropoints. Finally, the structure behavior relationship and corresponding mathematic model reflecting the relationship among hysteresis strain, stress and phase transformation strain were provided, which could predict the stress-strain behavior of the TiNi SMA joint to large extent.