论文部分内容阅读
The title complex, [Cu(Hsal)2(py)2], was synthesized by layered solution technique and structurally characterized by single crystal X ray. The copper atom has a square pyramidal geometry and the coordination number is five. The molecular structure is linear one dimensional network. There is a stacking effect between pyridine ligands of neighbouring 1 D chains and the molecular structure is extended into two dimensional stacking network. Two salicylates in the complex have a position of crab pincers like, in which one salicylate is unidentate and another coordinates through the carboxylate group and phenyl group unidentately.
The title complex, [Cu (Hsal) 2 (py) 2], was synthesized by layered solution technique and structurally characterized by single crystal X ray. The copper atom has a square pyramidal geometry and the coordination number is five. The molecular structure is linear one dimensional network. There is a stacking effect between pyridine ligands of neighboring 1 D chains and the molecular structure is extended into two dimensional stacking networks. Two salicylates in the complex have a position of crab pincers like, in which one salicylate is unidentate and another coordinates through the carboxylate group and phenyl group unidentately.