【摘 要】
:
Sodium-ion batteries are increasingly becoming important in the energy storage field owing to their low cost and high natural abundance of sodium.Cobalt-based s
【机 构】
:
Department of Chemistry,College of Sciences,Northeastern University,Shenyang 110819,Liaoning,China;D
论文部分内容阅读
Sodium-ion batteries are increasingly becoming important in the energy storage field owing to their low cost and high natural abundance of sodium.Cobalt-based sulfide materials have been extensively studied as anode materials owing to their remarkable Na storage capability.Nevertheless,the application of cobalt-based sulfides is hampered by their serious capacity degradation and unsatisfactory cycling stabil-ity due to severe structural changes during cycling.Therefore,it is important to comprehensively sum-marize advances in the understanding and modification of cobalt-based sulfides from various perspectives.In the present review,recent advances on various cobalt-based sulfides,such as CoS,CoS2,Co3S4,CogS8,NiCo2S4,CuCo2S4,and SnCoS4,are outlined with particular attention paid to strategies that improve their sodium storage performance.First,the mechanisms of charge storage are introduced.Subsequently,the key barriers to their extensive application and corresponding strategies for designing high-performance cobalt-based sulfide anode materials are discussed.Finally,key developments are summarized and future research directions are proposed based on recent advancements,aiming to offer possible fascinating strategies for the future promotion of cobalt-based sulfides as anode materials applied in sodium-ion batteries.
其他文献
Molybdenum phosphide(MoP),owing to its abundant reserve and high theoretical capacity,is regarded as a promising anode material for potassium-ion batteries.Howe
Aqueous rechargeable zinc-ion batteries(ZIBs)have recently attracted increasing research interest due to their unparalleled safety,fantastic cost competitivenes
A great deal of attention has been paid on developing plant-derived hard carbon(HC)materials as anodes for sodium-ion batteries(SIBs).So far,the regulation of H
Exploring electrode materials with a high volumetric energy density and high rate capability remains of a great challenge for nanosized-Li4Ti5O12(LTO)batteries.
Iron-based electrodes have attracted great attention for sodium storage because of the distinct cost effec-tiveness.However,exploring suitable iron-based electr
为解决焦炉煤气制LNG、甲醇等项目中预加氢、一级加氢、二级加氢样品中硫化物检测组分浓度差异大使得部分硫化物需要稀释进样的问题,采用价格低、普及性高的火焰光度检测器及填充柱气相色谱仪,通过减小定量环、改造信号放大组件、分段拟合等手段将直接进样检测焦炉煤气中形态硫的质量浓度检测范围拓宽至2.86~142.86 mg/m3。结果表明,在上述范围内一定浓度梯度进行复测,所得数据线性相关性高,满足相关标准要求。同时,该方法还能避免因焦炉煤气中各形态硫组分浓度差异大所造成的稀释后部分硫化物浓度过
Porous carbons were obtained from rice husk using two different chemical activation methods and they were investigated as supercapacitors.Their properties were studied using X-ray photoelectron spectroscopy,thermal analysis,potentiometric titration,and ni
Electrochemical nitrogen reduction reaction(NRR)is one of the most promising alternatives to the tradi-tional Haber-Bosch process.Designing efficient electrocat
采用带微型热导检测器的创新型气相色谱仪,选用不同的分析模块组合对模拟天然气中的组分进行快速分析。分析结果表明,在恒定温度条件下色谱可在85 s内完成天然气中常规组分的分析,分析重复性在1%以内;120 s内完成12组分硫化物气体组分的分析,检出限为0.5~2.0μmol/mol;H2S、COS、CH3SH、C2H5SH四种硫化物在5~60μmol/mol的浓度范围内线性相关性好(R2>0.9
Developing single-atom catalysts (SACs) for electrochemical devices is a frontier in energy conversion.The comparison of stability,activity and selectivity betw