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本文首次系统地应用软硬酸碱理论等阐明硝基配合物键合异构现象和它们的红外活性v(MN)波数变化规律,并对软硬酸碱理论作一些补充说明。还没有人系统地说明目前已合成的硝基配合物的键合异构现象。我们尝试着用软硬酸碱理论等对这现象加以概括。
In this paper, we first systematically applied the theory of soft and hard acid-base to elucidate the bonding isomerism of nitro complex and their variation of wavenumber of infrared activity v (MN), and make some supplements to the theory of soft and hard acid-base. No one has systematically described the bonding isomerism of nitro complexes that have been synthesized so far. We try to use soft and hard acid-base theory to summarize this phenomenon.