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5. Syntheses,structures,and reactivity of ruthenium(Ⅱ) hydride complexes containing Klui’s oxygen trip

Syntheses,structures,and reactivity of ruthenium(Ⅱ) hydride complexes containing Klui’s oxygen trip

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：smarten

【摘 要】

：

Treatment of Ru(CO)(Cl)(H)(PPh3)3 with NaLOEt (LOEt-= [CpCo{P(O)(OEt)2}3]-) afforded the hydride complex (PPh3)(CO)-LOEtRu(H) (1), which has been characterized

【作 者】

：

NG Ho-Yuen LAI Chun-Sing WILLI 

【机 构】

：

DepartmentofChemistry

【出 处】

：

中国科学：化学英文版

【发表日期】

：

2010年10期

【关键词】

：

RUTHENIUM OXYGEN TRIPODAL ligand hydride COMPLEX (arylsulfonyl)amido COMPLEX rut 

【基金项目】

：

supported by the Hong Kong Research Grants Council (602209)

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Treatment of Ru(CO)(Cl)(H)(PPh3)3 with NaLOEt (LOEt-= [CpCo{P(O)(OEt)2}3]-) afforded the hydride complex (PPh3)(CO)-LOEtRu(H) (1), which has been characterized by X-ray crystallography. Similarly, the tricyclohexylphosphine analogue, (PCy3)(CO)LOEtRu(H) (

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