一、前言功能化聚合物在有机合成上的应用是化学领域中近年来发展的一个重要方面。Ma-rrifild 曾成功的引用固相技术促进了多肽的合成。这一技术也被用于其它有机合成。选择适用的功能化聚合物以解决专门的合成问题(包括各种精细有机合成及多肽、糖、核苷酸、萜类,生物碱、激素等天然产物)的研究正在蓬勃兴起。功能化聚合物的适用性取决于聚合物的溶胀程度,有效孔隙大小及聚合物的机械稳定性等,其中最关键的是交联 I. INTRODUCTION The use of functionalized polymers in organic synthesis is an important aspect of the chemical field in recent years. Ma-rrifild has successfully cited the solid phase technology to promote the synthesis of peptides. This technique is also used in other organic synthesis. Research on the selection of suitable functionalized polymers to solve specialized synthesis problems, including various fine organic synthesis and natural products such as peptides, sugars, nucleotides, terpenes, alkaloids, hormones, etc., is booming. The suitability of the functionalized polymer depends on the degree of swelling of the polymer, the effective pore size and the mechanical stability of the polymer, among which the most critical is crosslinking