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近年来,我们发现一些染料分子表现出了多性能性,如Squaraine,它不仅具有相当好的非线性光学性质,而且因具有好的光电性质已成为材料进入应用,我们在研究多种染料体系中同时发现了它们优良的二阶非线性光学性质和光电化学性质,本文研究的氮杂芪唑盐是专为研究分子的二阶非线性活性理论而设计的一个化合物,它具有比Squaraine更好的二次谐波产生能力,我们对其作为光电材料的光电化学性质进行了研究,并就其光电转换的可能机理进行了探讨,在仿生材料中,LB膜方法是一种极为恰当和有效的方法,它有望克服无机固体器件的体积限制而产生新的功能.
In recent years, we have found that some dye molecules exhibit multi-performance properties, such as Squaraine, which not only possesses rather good nonlinear optical properties, but also has been used as a material due to its good optoelectronic properties. At the same time, we found their excellent second-order nonlinear optical properties and photoelectrochemical properties. The azaserzasalt salt studied in this paper is a compound designed to study the second-order nonlinear activity theory of molecules. It has better properties than Squaraine Second harmonic generation ability, we have carried out research on its photoelectrochemical properties as a photoelectric material, and discussed its possible mechanism of photoelectric conversion. In the bionic material, LB film method is a very appropriate and effective method , It is expected to overcome the volume limitations of inorganic solid-state devices to produce new functions.