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链状多胺的末端芳基化SciafaniJA等[JOrgChem,1996;61:3221]链状多胺H2NCH2(CH2NHCH2)nCH2NH2(n=1~3)与2当量的芳醛在氯仿溶液中反应,两端形成芳基亚胺,反应条件视芳醛而定。亚胺不经分离,以过量Na...
Terminal Arylation of Chain Polyamines Sciafani JA et al [JOrg Chem, 1996; 61: 3221] The chain polyamine H2NCH2 (CH2NHCH2) nCH2NH2 (n = 1-3) is reacted with 2 equivalents of the aryl aldehyde in a chloroform solution at both ends Formation of arylimine, the reaction conditions depending on the arylaldehyde. Imine without isolation, with excess Na ...