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[Cu2( -C-N-C6H4CH3-p)4(DMF)2]-4DMF(1), Mr = 1582.7, triclinic,Pl, a = 10.761(1), b = 13.930(3), c = 15.116(3) A;α= 114.74(1),β= 101.82 (1),r= 95.85(1)°,V = 1969.0 A3,Z=1,Dm= 1.36,DC =1.335 g/cm3.[Cu2(-C-N-C6H4Ch3-M)4.(DF)2].4DMF(2), Mr = 1582.7, triclinic, Pl,a = 10.588(5), b = 13.699(2), c = 15.759(4) A;α= 114.88(2),β= 103.89(3), γ=92.56(3)°, V =1985.3 A3, Z = 1, 0. = 1.39,Dc= 1.324 g/cm3.The four phthalamine groups in molecules of (1) and (2) are all biden-tate bridging ligands to Cu atoms and there are two terminal DMF ligands, one on each Cu atom. The Cu-Cu distances are 2.635(1) and 2.641(1) A for (1) and (2) respectively.
[Cu2 (-CN-C6H4CH3-p) 4 (DMF) 2] -4DMF (1), Mr = 1582.7, triclinic, Pl, a = 10.761 (1), b = 13.930 (3), c = A = 114.74 (1), β = 101.82 (1), r = 95.85 (1) °, V = 1969.0 A3, Z = 1, Dm = 1.36, DC = 1.335 g / cm3 [Cu2 (-CN- C6H4Ch3-M) 4. (DF) 2] .4DMF (2), Mr = 1582.7, triclinic, Pl, a = 10.588 (5), b = 13.699 (2), c = 15.759 (4) A; (2) β = 103.89 (3), γ = 92.56 (3) °, V = 1985.3 A3, Z = 1, 0. = 1.39, Dc = 1.324 g / cm 3 The four phthalamine groups in molecules of (1) (2) are all biden-tate bridging ligands to Cu atoms and there are two terminal DMF ligands, one on each Cu atom. The Cu-Cu distances are 2.635 (1) and 2.641 (1) A for (1) and 2) respectively.