Particulate pollution is a serious health problem throughout the world, exacerbating a wide range of respiratory and vascular illnesses in urban areas. Urban plants play an important role in reducing particulate pollution. Physicochemical characteristics of ambient particles settling upon leaf surfaces of eleven roadside plants at four sites of Beijing were studies. Results showed that density of particles on the leaf surfaces greatly varied with plant species and traffic condition. Fraxinus chinensis, Sophora japonica, Ailanthus altissima, Syringa oblata and Prunus persica had larger densities of particles among the tall species. Due to resuspension of road dust,the densities of particles ofEuonymus japonicus and Parthenocissus quinquefolia with low sampling height were 2-35 times to other taller tree species. For test plant species, micro-roughness of leaf surfaces and density of particles showed a close correlation. In general, the larger micro-roughness of leaf surfaces is, the larger density of particles is. Particles settling upon leaf surfaces were dominantly PM10 (particulate matter less than 10 μm in aerodynamic diameter; 98.4%) and PM2.5 (particulate matter less than 2.5 μm in aerodynamic diameter; 64.2%) which were closely relative to human health. Constant elements of particles were C, O, K, Ca, Si,earth dust or industrial emission and SO2, H2SO4 or sulfate. NaCl was derived from sea salt.