半花菁LB多层膜的光致各向异性研究

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用光学线性(偏振紫外-可见吸收)和非线性(旋转样品二次谐波)方法研究了Y型半花菁/花生酸交替LB多层膜的光致光学各向异性。在纳秒紫外偏振脉冲激光照射下,LB多层膜中半花菁分子发色团长轴向紫外光偏振方向重新取向。加热可以使LB多层膜平面内各向异性消失及H-聚集体分解 Photoinduced optical anisotropy of a Y-type hemicyanine / arachidic alternating LB multilayer films was studied by optical linearity (Polarization UV-Vis absorption) and nonlinearity (Rotating Sample Second Harmonicity). Under the nanosecond UV-pulsed laser irradiation, the polarization direction of the long-axis UV light of the hemicyanine molecule in the LB multilayer film is reoriented. Heating can make the LB multilayer film disappear in the plane anisotropy and H-aggregate decomposition
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