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The title complex with benzilic acid and 1,10-phenanthroline monohydrate has been synthesized and characterized in the solvent mixture of water and methyl-alcohol. It falls into the triclinic, characteristic of the space group P1 with a=1.142 8(3) nm, b=1.638 8(4) nm, c=1.645 6(4) nm, α=74.428(5)°, β=84.205(5)°, γ=74.917(5)°, V=2.864 9(12) nm3, Dc=1.347 g·cm-3. Z=2, F(000)=1 216, the reliability factor R1=0.068 9, wR2=0.189 9. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from the three phens, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 274184.
The title complex with benzilic acid and 1,10-phenanthroline monohydrate has been synthesized and characterized in the solvent mixture of water and methyl-alcohol. It falls into the triclinic, characteristic of the space group P1 with a = 1.142 8 (3) nm , b = 1.638 8 (4) nm, c = 1.645 6 (4) nm, α = 74.428 (5) °, β = 84.205 (5) °, the reliability factor R1 = 0.068 9, and the value of wR2 = 0.189 9. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms (nm), Dc = 1.347 g · cm -3 from the three phens, forming a distorted octahedral coordination geometry. The cyclic voltame behavior of the complex is also reported. CCDC: 274184.