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A new cooper benzenedicarboxylate metal-organic coordination polymer,[Cu(μH2O)(BDC)]n·nDMF(1,H2BDC = 1,4-benzenedicarboxylate acid,DMF = N,N’-dimethylfor-mamide),has been successfully synthesized under hydrothermal conditions and characterized by IR spectroscopy,elemental analysis,thermogravimetric analysis and single-crystal X-ray diffraction.This complex crystallizes in triclinic,space group P1 with a = 6.605,b = 10.44780(10),c = 11.0881(6) ,α = 62.064(11),β = 73.410(15),γ = 78.404(16)°,C11H13CuNO6,Mr = 318.76,V = 645.79(8) 3,Z = 2,Dc = 1.639 g/cm3,F(000) = 326,μ = 1.712 mm-1,the final R = 0.0362 and wR = 0.1330 for 2055 observed reflections with I > 2σ(I).The title compound contains infinite inorganic chains constructed by Cu oxygen octahedra by sharing corners and edges.Each chain is connected by BDC linkers to four other chains to form a three-dimensional framework with irregular rhombic channels where the DMF molecules are encapsulated.
A new cooper benzenedicarboxylate metal-organic coordination polymer, [Cu (μH2O) (BDC)] n · nDMF (1, H2BDC = 1,4-benzenedicarboxylate acid, DMF = N, N’-dimethylfor- mamide) under hydrothermal conditions and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis and single-crystal X-ray diffraction. This complex crystallizes in triclinic space group P1 with a = 6.605, b = 10.44780 (10), c = 11.0881 , α = 62.064 (11), β = 73.410 (15), γ = 78.404 (16) °, C11H13CuNO6, Mr = 318.76, V = 645.79 83, Z = 2, Dc = 1.639 g / cm3, The final R = 0.0362 and wR = 0.1330 for 2055 at reflections with I> 2σ (I). The title compound contains an infinite inorganic chains constructed by Cu oxygen octahedra by sharing corners and edges. Each chain is connected by BDC linkers to four other chains to form a three-dimensional framework with irregular rhombic channels where the DMF molecules are encapsulated.