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A.H.Fainberg等人对特丁基氯的溶剂解反应动力学进行了大量的实验研究,在此基础上,本文应用定标粒子理论对其进行理论分析和计算。结果表明,理论计算与实验结果具有相当好的一致性。最后还就溶剂对反应动力学的影响规律和机理进行了讨论。
A.H.Fainberg et al. Have done a lot of experimental studies on the solvent-reaction kinetics of terbutylchloride. On the basis of this, this paper uses the theory of scaled particle theory to analyze and calculate the kinetics. The results show that the theoretical calculation and experimental results have quite good agreement. Finally, the influence of solvent on the reaction kinetics and the mechanism were discussed.