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实验研究了氟磷玻璃中[PO3]-含量的变化对Yb3+的光谱性质的影响。结果表明.随着[PO3]-含量的增大,Yb3+的受激发射截面积增大,吸收光谱和荧光光谱谱线位置向长波方向移动,反映出Nephelauxetic效应。随[PO3]-含量增大,玻璃中引入的OH-离子浓度增大,极大降低了Yb3+荧光寿命。
The effect of [PO3] - content on the spectral properties of Yb3 + was investigated experimentally. The results show. With the increase of [PO3] - content, the stimulated emission cross section of Yb3 + increases, and the positions of absorption and fluorescence spectra shift to the longwave, which reflects the Nephelauxetic effect. With the increase of [PO3] - content, the concentration of OH- ions introduced into the glass increases, greatly reducing the fluorescence lifetime of Yb3 +.