【摘 要】
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测定了二氰基二硫纶.邻菲咯啉-5,6-二酮混配锰(Ⅱ)、铁(Ⅱ)、钴(Ⅱ)配合物MLL′(M=Mn2+、Fe2+、Co2+;L=mnt2-,1,2-二氰基乙烯-1,2-二硫醇离子;L′=phen-5,6-dione,1,10-邻菲
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测定了二氰基二硫纶.邻菲咯啉-5,6-二酮混配锰(Ⅱ)、铁(Ⅱ)、钴(Ⅱ)配合物MLL′(M=Mn2+、Fe2+、Co2+;L=mnt2-,1,2-二氰基乙烯-1,2-二硫醇离子;L′=phen-5,6-dione,1,10-邻菲咯啉-5,6-二酮)在二甲基亚砜(DMSO)、丙酮(Acet)和氯仿(CHCl3)中的电子吸收光谱,研究了电子光谱吸收带在相关分子轨道能级图中的对应跃迁关系,探讨了它们在DMSO中的感光氧化特性。
The dicyanodisulfide was synthesized by the reaction of 1,10-phenanthroline-5,6-dione with MLL (M = Mn2 +, Fe2 +, Co2 + = mnt2-, 1,2-dicyanoethylene-1,2-dithiol ion; L ’= phen-5,6-dione, 1,10-phenanthroline-5,6-dione) The corresponding absorption transitions of the electron absorption bands in the molecular orbital energy level diagrams were studied by the electron absorption spectra in dimethyl sulfoxide (DMSO), acetone (Acet) and chloroform (CHCl3) Photooxidation properties.
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