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A novel mercury(n)complex HgL_2Br_2 was prepared from HgBr_2 and the organic ligand 2-(N-methyl-N-(4-((E)-2-(pyridine-4-yl)vinyl)phenyl)amino)ethanol(L).The ligand was synthesized and then characterized by FT-IR spectroscopy,~1H NMR,mass spectrum and elemental analysis,while the single-crystal diffraction data of the complex were collected on a Siemens Smart CCD diffractometer.The complex crystallizes in triclinic space group P_1~-with a=5.367(5),b= 12.466(5),c=23.945(5)(?),α=90.812(5),β=96.318(4),γ=96.093(5)°,Z=2,D_c=1.817g·cm~(-3),μ=7.395 mm~(-1),S=0.825,and the final R=0.0396.The Hg(Ⅱ)ion in the distorted tetrahedral mercury(Ⅱ)complex C_(32)H_(36)HgBr_2N_4O_2 is coordinated by two N atoms from the two ligands together with two bromide ions.Solid-state emission of the ligand and its complex has been investigated at room temperature.
A novel mercury (n) complex HgL_2Br_2 was prepared from HgBr_2 and the organic ligand 2- (N-methyl-N- (4 - ((E) -2- L). The ligand was synthesized and then characterized by FT-IR spectroscopy, ~ 1H NMR, mass spectrum and elemental analysis, while the single-crystal diffraction data of the complex were collected on a Siemens Smart CCD diffractometer. The complex crystallizes in triclinic Space group P_1 ~ -with a = 5.367 (5), b = 12.466 (5), c = 23.945 (5),? = 90.812 (5),? = 96.318 (4),? = 96.093 (5) °, Z = 2, D_c = 1.817g · cm -3, μ = 7.395 mm -1, S = 0.825, and final R = 0.0396.The Hg (Ⅱ) ion in the distorted tetrahedral mercury (Ⅱ) complex C_ (32) H_ (36) HgBr_2N_4O_2 is coordinated by two N atoms from the two ligands together with two bromide ions. Solid-state emission of the ligand and its complex has been investigated at room temperature.