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用改良的Hummers法制备出氧化石墨烯(GO),再通过溶液共混,逐步升温固化制备得到GO/呋喃树脂复合材料。利用FTIR、XRD和SEM对GO/呋喃树脂复合材料的微观结构和形貌进行表征,同时对其黏度、玻璃化转变温度、热分解温度、残炭率及硬度进行了检测。结果表明,GO较均匀地分散于呋喃树脂基体中,且两者界面相容性较好。GO/呋喃树脂复合材料的热性能和力学性能相对于纯树脂都有一定的提高。与纯呋喃树脂相比,当GO的添加量为0.3wt%时,GO/呋喃树脂复合材料的玻璃化转变温度提高了36℃,热失重5%时的温度提高了16℃;当GO的添加量为0.1wt%时,GO/呋喃树脂复合材料的残炭率从50.7%提高到53.9%,邵氏硬度从90提高到97。
Graphene oxide (GO) was prepared by a modified Hummers method, and then GO / furan resin composites were obtained through the solution blending and temperature curing. The microstructure and morphology of GO / furan resin composites were characterized by FTIR, XRD and SEM, and the viscosity, glass transition temperature, thermal decomposition temperature, carbon residue rate and hardness were measured. The results show that GO is more evenly dispersed in furan resin matrix, and the interface between the two is better. GO / furan resin composite thermal properties and mechanical properties relative to pure resin has a certain increase. Compared with the pure furan resin, the GO / furan resin composites increased the glass transition temperature by 36 ℃ and the temperature at 5% weight loss by 16 ℃ when the addition amount of GO was 0.3wt% The carbon residue rate of GO / furan resin composites increased from 50.7% to 53.9% and the Shore hardness increased from 90 to 97 at 0.1 wt%.