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研究了在吐温-80存在下锗与邻硝基苯基荧光酮的显色反应。结果表明,在HCl介质中,锗与邻硝基苯基灾光酮形成了灵敏度很高的络合物。其ε=1.43x105组成比Ge(Ⅳ):邻硝基苯基荧光酮=1:3.在掩蔽剂存在下,可不经分离测定铝合金和阳极泥中的锗,结果令人满意。
The color reaction of germanium with o-nitrophenylfluorone in the presence of Tween-80 was studied. The results show that germanium forms a highly sensitive complex with o-nitrophenylketone in the HCl medium. The ε = 1.43x105 composition ratio of Ge (Ⅳ): o-nitrophenylfluorone = 1: 3. In the presence of a masking agent, the determination of germanium in the aluminum alloy and anode slime without isolation was satisfactory and the results were satisfactory.