【摘 要】
：
Urea(CO(NH2)2)is a globally abundant waste product in accompany with industrial activities and naturally breaks down into ammonia(NH3)and nitrate.Nowadays,over 80％of these pollutants are discharged directly into rivers and oceans,causing significant healt
【机 构】
：
Key Laboratory for Soft Chemistry and Functional Materials(Ministry of Education),School of Chemistr
论文部分内容阅读
Urea(CO(NH2)2)is a globally abundant waste product in accompany with industrial activities and naturally breaks down into ammonia(NH3)and nitrate.Nowadays,over 80％of these pollutants are discharged directly into rivers and oceans,causing significant health and environmental pro-blems[1].As a consequence,there are enormous interests in urea oxidation reaction(UOR).UOR is a central half-reac-tion in urea electrolysis and urea-based fuel cells that can treat urea-rich wastewater simultaneously[1].Further,UOR only needs a thermodynamic potential of 0.37 V that is much lower than 1.23 V for oxygen evolution reaction(OER),which allows it to be an alternative of OER in water splitting.Therefore,UOR can combine hydrogen evolution reaction(HER)to allow for cheaper hydrogen production[2].In a similar way,UOR can be used as anodic reaction coupling with the reactions such as CO2 reduction,O2 reduction and N2 reduction to improve the energetic efficiency of overall systems[3].
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