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The copper(Ⅱ) compound [Cu(Br2hama)(DMF)]2 (C22H24Br4Cu2N4O10S2,Br2hamaH2 = [(3,5-dibromo-2-hydroxybenzylidene)-amino]-methanesulfonic acid,DMF = N,Nˊ-dimethylfor-mamide) 1 crystallizes in triclinic,space group P1 with a = 8.477(2),b = 10.164(2),c = 10.67