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用脱氧剂非真空环境下Ｓｔｏｃｋｂａｒｇｅｒ方法生长未掺和掺铈、镧、铕的浓度范围在１００～５０００ｐｐｍｗｔ的ＢａＦ２晶体．脱氧剂生长方法具有设备简单，不用抽真空和批量生产透明大单晶的特点．测量了这些晶体在室温下透射、激发，以及Ｘ射线和紫外光激发的发射光谱．由Ｘ射线激发，掺杂１０００ｐｐｍ的Ｃｅ样品具有峰值在３０７ｎｍ和３２１ｎｍ二个发射带，被归为放没有其它邻近铈离子条件下Ｃｅ（３＋）的５ｄ－４ｆ跃迁．对于掺杂５０００ｐｐｍ的Ｃｅ晶体，新的发射带出现在峰值为３４０ｎｍ的３２６～３７５ｎｍ范围．新的发射带仍是Ｃｅ（３＋）离子５ｄ－４ｆ跃迁引起的，与其它邻近Ｃｅ离子相互作用，使５ｄ能级朝着较低能量迁移．１０００ｐｐｍ的样品具有最大发光强度，以及闪烁波长＞３００ｎｍ具有封闭电子壳层外加阳离子Ｌａ（３＋）很少影响心一价带跃迁（ＣＶＴ），但是降低慢分量（激子）发射强度．ＢａＦ２：１ｗｔ％Ｌａ样品的快／慢分量比＞纯的样品的快／慢分量比．镧杂质抑制慢分量，并保持未掺ＢａＦ２辐照硬度．Ｘ射线激发ＢａＦ２：１００ｐｐｍＥｕ发射光谱呈现二个部分：相对强的３００ｎｍ本征慢分量发光，以及～４３０和５９０ｎｍＥｕ（２＋）离子二个特征弱?
Growth of un-doped BaF2 crystals doped with cerium, lanthanum and europium in the concentration range of 100-5000 ppmwt was carried out by the Stockbarger method under a non-vacuum environment using a deoxidizer. Deoxidizer growth method with simple equipment, without vacuum and mass production of large transparent single crystal. The emission spectra of these crystals were measured at room temperature for transmission, excitation, and X-ray and UV excitation. Excited by X-rays, a 1000 ppm doped Ce sample has two emission bands with peaks at 307 nm and 321 nm and is classified as a 5d-4f transition of Ce (3+) without other nearby cerium ions. The new emission band appeared in the 326 to 375 nm peak at 340 nm for 5000 ppm doped Ce crystals. The new emission band is still caused by the 5d-4f transition of Ce (3+) ions, interacting with other neighboring Ce ions, causing the 5d energy level to migrate toward lower energies. The 1000 ppm sample has the maximum luminescence intensity, and the blinking wavelength> 300 nm with a closed electron shell plus cation La (3+) seldom affects the CVT, but slows the emission of the slow (exciton) emission. BaF2: Fast / Slow Component Ratio of 1 wt% La Sample> Fast / Slow Component Ratio of Pure Sample. The lanthanum impurity inhibits slow components and keeps the hardness of the un-doped BaF2 irradiated. X-ray excitation BaF2: 100ppmEu emission spectrum presents two parts: relatively strong 300nm intrinsic slow component luminescence, and ~ 430 and 590nmEu (2+) ion two characteristics of weak?