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The crystal and molecular structure of [ Ag2 (ETU) 6 ] @ (ClO4) 2 has been determined by X-ray crystallography.It crystallizes in the monoclinic, space group P21/c, with lattice parameters a = 0. 63270(9)nm, b = 2. 4264(2)nm, c=1.2128(1) nm, β=92.721(9)