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A complex [Mn(2,4-DAA)2(4,4'-bipy)]n with 2,4-dichlorophenoxy acetic acid and 4,4'-bipy has been synthesized and characterized. It crystallizes in the monoclinic space group C2/c with a=2.307 8(6) nm, b=1.164 3(3) nm, c=0.970 9(3) nm, β=96.249(5)&