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研究了不同实验条件下甲酸在旋转圆盘Pt电极上氧化的循环伏安图,发现在循环伏安图上的阴极扫描过程出现了2个峰取代了通常观察到的单峰,解析了这些峰产生的原因是由于羰基吸附物的氧化,并提出了新的机理。
The cyclic voltammograms of formic acid oxidation on the Pt electrode of a rotating disk were investigated under different experimental conditions. It was found that two peaks appeared on the cyclic voltammogram during cathodic scan, replacing the normally observed single peak. These peaks were analyzed The reason for this is due to the oxidation of the carbonyl adsorbate, and a new mechanism is proposed.