3D free bending process, an advanced metal forming technology, has attracted much attention due to its unique geometrical flexibility and efficiency. Filling tubes with materials may effectively reduce the distortion in the cross-section area and restrain wrinkling and collapse of tube wall. In the present study, the impacts of filling different materials on the copper tubes during 3D free bending process were investigated. We have found that copper tubes filled with low melting point alloys could induce the most uniform stress distribution, which result in better formability and moderate thickness changing rates when compared to SS304 steel balls and PU rubbers. The lowest ellipticity reached to 1.467％.