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一、引言已有许多关于铜基和银基有机固体电解质的报道,其最佳离子电导率值在室温可达10~(-2)(Ωcm)~(-1)数量级。我们用六次甲基四胺的氢碘酸盐C_6H_(12)N_4HI与碘化银AgI反应制得的固体电解质,25℃时电导率为7.5×10~(-2)(Ωcm)~(-1)。比Takahashi等人用六次甲基四胺的氢碘酸盐C_6H_(12)N_4·HI与碘化亚铜CuI反应制得的固体电解质,及Owens等人用六次甲基四胺的氢氨酸盐C_6H_(12)N_4·HCl与氯化亚铜CuCl反应制成的固体电解质的电导率,都高一个数量级。用NNN’N’-四甲基乙烯二胺的碘氢酸盐C_6H_(16)N_2·2HI同AgI反应,制成了固体电解质,25℃时电导率值为1.01×10~(-2)(Ωcm)~(-1),达到季胺盐类固体电解质的最佳电导率值。
I. INTRODUCTION There have been many reports on copper-based and silver-based organic solid electrolytes. The best ionic conductivity value is about 10 ~ (-2) (Ωcm) ~ (-1) at room temperature. We use hexamethylenetetramine hydroiodide salt C_6H_ (12) N_4HI and silver iodide AgI reaction of solid electrolyte, 25 ℃, the electrical conductivity of 7.5 × 10 -2 (Ωcm) -1 . A solid electrolyte prepared by the reaction of hexamethylenetetramine hydroiodide salt C_6H_ (12) N_4 · HI with cuprous iodide CuI by Takahashi et al., And hydrogen ammine with Hexamethylenetetramine by Owens et al. The conductivity of the solid electrolyte made from the reaction of the acid salt C 6 H 12 N 4 · HCl with cuprous chloride CuCl is an order of magnitude higher. The solid electrolyte was prepared by reaction of C_6H_ (16) N_2 · 2HI, an iodine hydrogenate of NNN’N’-tetramethylethylenediamine with AgI, and its conductivity was 1.01 × 10 ~ (-2) at 25 ℃ Ωcm) ~ (-1), the quaternary ammonium salt solid electrolyte to achieve the best conductivity value.