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  5. The synthesis, self-assembly and electrocatalytic property of a novel disulphide derivatised cobalt(

The synthesis, self-assembly and electrocatalytic property of a novel disulphide derivatised cobalt(

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：seasports
【摘 要】
：
A novel disulphide derivatised deuteroporphyrin 2,7,12,18-tetramethyl-13,17-(propionylaminoethyldithioethyl amino-formylethyl)-29,34-bis-(methoxyformyl)porphyri
【作 者】
：
Shi Chao Xu Bing Cheng Hu Wei 
【机 构】
：
School of Chemical Engineering
【出 处】
：
中国化学快报（英文版）
【发表日期】
：
2004年期
【关键词】
：
Deutorporphyrin Disulphide derivate Electrocatalysis Self-assembly 
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论文部分内容阅读
A novel disulphide derivatised deuteroporphyrin 2,7,12,18-tetramethyl-13,17-(propionylaminoethyldithioethyl amino-formylethyl)-29,34-bis-(methoxyformyl)porphyrin (PDTEP.3) and its cobalt(Ⅱ) complex (Co(Ⅱ)PDTEP.4) were conveniently synthesized.The disulphide functional group of 4 allowed its stable immobilization on gold electrodes.The modified electrode was characterized by IR and confirmed electrochemically and showed good stability and catalytic activity toward the electro-catalyzed reduction of hydrogen peroxide.
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