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本文介绍近年来国外金属有机化学家报道的烷基及芳基三氧合铼（１４ｅ，ＶＩＩ）络合物ＲＲｅＯ＿３的合成和反应，以及利用该类络合物催化的烯烃歧化、烯烃环氧化和醛与重氮化合物烯烃化反应。
In this paper, the synthesis and reaction of alkyl and aryl rhenium (14e, VII) complexes RReO_3 reported by foreign metal organic chemists reported in recent years are reviewed. And the methods of olefin disproportionation and olefin epoxidation And aldehyde and diazo compound olefination.