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A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with a = 8.182(2), b = 12.874(3), c = 15.611(4) ? V = 1644.4(7) 3, Dc = 1.425 g/cm3, Z = 4, Mr = 352.78, m(MoKa) = 0.944 mm-1, F(000) = 736, S = 1.036, the final R = 0.0521 and wR = 0.1187 for 1128 observed reflections (I > 2s(I)). An infinite one-dimensional zigzag chain is formed by NH…N hydrogen bonding interactions between the imidazolium salt cations.
A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di (imidazol-1-ylmethyl) -5-methylbenzene, and characterized by X- ray analysis. It is of orthorhombic, space group Pnma with a = 8.182 (2) b = 12.874 (3) c = 15.611 (4) V = 1644.4 (7) 3 Dc = 1.425 g / cm3 Z = 4 Mr = 352.78 m MoKa = 0.944 mm -1, F (000) = 736, S = 1.036, the final R = 0.0521 and wR = 0.1187 for 1128 observed reflections (I> 2s (I)). An infinite one-dimensional zigzag chain is formed by NH ... N hydrogen bonding interactions between the imidazolium salt cations.