Unique chemical properties of metal-carbon bonds in metal-carboranyl and metal-carboryne complexes

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：juliediar

【摘要】

：

The metal-carbon bonds in metal-carboranyl and metal-carboryne complexes behave very differently from those in classical organometallic complexes. The unique el

【作者】

：

ZaoZao Qiu (1) ZuoWei Xie (

【机构】

：

1.DepartmentofChemistry

【出处】

：

中国科学：化学英文版

【发表日期】

：

2009年10期

【关键词】

：

BORON cluster CARBORANE carboryne INSERTION metal-carbon BOND boron cluster carb

【基金项目】

：

Supported by the Research Grants Council of the Hong Kong Special Administration Region (Grant No. 404108)

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The metal-carbon bonds in metal-carboranyl and metal-carboryne complexes behave very differently from those in classical organometallic complexes. The unique electronic and steric properties of ico-sahedral carboranyl moiety make the M-C bond in metal-car

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Unique chemical properties of metal-carbon bonds in metal-carboranyl and metal-carboryne complexes

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