合成了Ｔｂ（ＤＰＳＯ）６·（ＣｌＯ４）３、Ｔｂ（ＤＰＳＯ）７·（ＰＦ６）３及Ｔｂ（ＰＢＳＯ）６·（ＣｌＯ４）３配合物（ＤＰＳＯ为二苯基亚砜ＰＢＳＯ为苯丁基亚砜）．在室温下测定了它们的固体粉末荧光激发和发射光谱，结果表明Ｔｂ（ＤＰＳＯ）６·（ＣｌＯ４）３配合物中Ｔｂ３＋的发光强度最高，其中５Ｄ４→７Ｆ５跃迁谱带强度高达８０６．２ｃｄ，Ｔｂ（ＤＰＳＯ）７（ＰＦ６）３配合物中Ｔｂ３＋发光强度次之，Ｔｂ（ＰＢＳＯ）６（ＣｌＯ４）３配合物中Ｔｂ３＋的发光强度最弱．这说明二苯亚砜做为配体受激后向Ｔｂ３＋离子传递能量的效率高于苯丁基亚砜，另外ＣｌＯ４－做为阴离子也可增加Ｔｂ３＋的发光强度，原因是部分外界ＣｌＯ４－离子可进入内界参予配位，降低了配合物的对称性，部分解除了跃迁禁律，提高了Ｔｂ３＋的发光强度． The complexes of Tb (DPSO) 6 · (ClO4) 3, Tb (DPSO) 7 · (PF6) 3 and Tb (PBSO) 6 · (ClO4) 3 were synthesized. DPSO is diphenylsulfoxide PBSO is phenylbutylidene Sulfone). The fluorescence excitation and emission spectra of Tb3 + in Tb (DPSO) 6 · (ClO4) 3 complex were measured at room temperature. The intensity of 5D4 → 7F5 transition band is up to 806.2cd, Tb Tb3 + in Tb (PBSO) 6 (ClO4) 3 complex, the emission intensity of Tb3 + in Tb (PBSO) 6 (ClO4) 3 complex is the weakest. This shows that as a ligand ligand, BTPA is more effective in delivering energy to Tb3 + ions than phenylbutyl sulfoxide. In addition, ClO4- can also increase the luminescence intensity of Tb3 + because some ClO4- ions Into the interior to participate in coordination, reducing the symmetry of the complex, partially lifted the ban on the transition, increased the luminous intensity of Tb3 +.