以多聚磷酸为催化剂,通过环十二碳烯和α,β-不饱和酸的反应,合成了十个双环[10.3.0]十五碳-1(12)-烯-13-酮系列化合物,研究了合成反应的条件及产物的分离提纯方法,并测定了它们的紫外光谱、红外光谱以及~1H核磁共振谱。 Ten polycyclic [10.3.0] pentadec-1 (12) -en-13-one series compounds were synthesized by the reaction of cyclododecene and α, β-unsaturated acids using polyphosphoric acid as catalyst , The conditions of the synthesis reaction and the methods for the separation and purification of the products were studied. Their UV spectra, IR spectra and 1H nuclear magnetic resonance spectra were also measured.