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N—苄基二茂铁磺酰胺[C_5H_5 FeC_5 H_4SO_2 NHCH_2C_6H_5]为黄色棱柱状晶体,属单斜晶系,空间程群P2/a,晶胞参数为:a=10.178(8),b=12.503(1),c=13.222(8)A,β=107.42(8)°,v=1605.57A~3,z=4,计算密度D_c=1.469g/cm~3。在SYNTEXR_3 四园衍射仪上,用M_0K_a射线收集数据,用SHELXTL—83直接法程序求解晶体结构。最后偏离因子R=0.0431,R_w=0.0426。对分子的几何特征及s原子配位情况作了讨论。
N-benzyl ferrocene sulfonamide [C_5H_5FeC_5H_4SO_2NHCH_2C_6H_5] is a yellow prism crystal and belongs to the monoclinic space group P2 / a. The unit cell parameters are: a = 10.178 (8), b = 12.503 1), c = 13.222 (8) A, β = 107.42 (8) °, v = 1605.57A ~ 3, z = 4 and the calculated density D_c = 1.469g / cm ~ 3. In the SYNTEXR_3 four-Park diffractometer, the data was collected with M_OK_a and the crystal structure was solved using the SHELXTL-83 direct method. The final deviation factor R = 0.0431, R_w = 0.0426. The geometry of the molecule and the coordination of s atoms are discussed.