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The complexes of zinc chloride and zinc nitrate with 2-amino-4, 6-dimethyl-pyrimidine (ADMP) were preparedthrough reflux in alcohol. The compositions of the complexes Zn(ADMP)2Cl2 (b) and Zn(ADMP)2(NO3)2 @ 4H2O(c) were determined by chemical and elemental