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系统概述了二十面体闭笼型硼氢阴离子B12H2-12及火炸药研究中的相关化合物的制备、热行为、热化学、能量性质;展望了此类多硼氢化合物在此领域中的应用前景.指出未来多硼氢化合物推进剂研究的主要方向为:以理论计算为基础,以多硼氢化合物完全燃烧为目标,设计、合成、筛选出在火炸药体系中高效率释放其固有能量的新的高能和超高能B12H2-12 离子衍生物.附参考文献158篇.“,”The preparation, thermal behavior, thermochemistry, energy properties of icosahedronal closo-hydroborate anion B12H2-12 and related compounds in the study of propellants and explosives were systematically reviewed.The application prospect of this kind of polyhydroborate compounds in this field is prospected.Pointing out that based on theoretical calculation, taking the complete combustion of polyhydroborate compounds as target, the design, synthesis and screening of new B12H2-12 ion derivatives with high energy and ultra high energy of highly efficient release intrinsic energy in propellants and explosives system should be the main directions of future research in polyhydroborate compound propellants,with 158 references.