微孔碳是无序固体,气体在其上的吸附,受到其孔结构不均匀性的强烈影响。非均匀性固体上的吸附模型,通常是由下式表示的吸附等温线GAI: (?)式中:θ为气体压力p下的、由实验确定的总吸附等温线。f为吸附能分布函数。GAI是第一类线性Fredholm积分方程。它的求解是个较大的难题,因为根本不同的分布会造成极其相似的总的等温线。解GAI的一般途 Microporous carbon is a disordered solid, on which gas is adsorbed, strongly influenced by the heterogeneity of its pore structure. The non-uniform adsorption model on a solid, usually the sorption isotherm, GAI, is given by: where θ is the experimentally determined total adsorption isotherm at gas pressure p. f is the adsorption energy distribution function. GAI is the first linear Fredholm integral equation. Its solution is a big problem because fundamentally different distributions result in very similar overall isotherms. GAI solution to the general way