论文部分内容阅读
采用复合功能单体制备了苯甲氧羰基－Ｌ－丝氨酸（Ｎ－Ｃｂｚ－Ｌ－Ｓｅｒ）和苯甲氧羰基－Ｌ－丙氨酸（Ｎ－Ｃｂｚ－Ｌ－Ａｌａ）烙印的分子烙印手性固定相。采用柱串联的方法，一次进样手性分离了苯甲氧羰基－ＤＬ－丝氨酸（Ｎ－Ｃｂｚ－ＤＬ－Ｓｅｒ）和苯甲氧羰基－ＤＬ－丙氨酸（Ｎ－Ｃｂｚ－ＤＬ－Ａｌａ）两对对映体，显示了分子烙印手性固定相在多对对映体同时手性分离的发展潜力。
The molecular imprinting chirality of the benzyloxycarbonyl-L-serine (N-Cbz-L-Ser) and benzyloxycarbonyl-L-alanine (N-Cbz-L-Ala) Stationary Phase. Benzyl oxycarbonyl-DL-serine (N-Cbz-DL-Ser) and benzyloxycarbonyl-DL-alanine (N-Cbz-DL-Ala) were chirally separated by one- Two pairs of enantiomers show the potential of molecularly imprinted chiral stationary phases for simultaneous chiral separation of multiple enantiomers.