The relationship between compressive strength obtained by universal testing machine and rebound value obtained by the hammer of high performance concrete was systematically investigated at the macro level. And a model of high performance concrete strength curve was established from them. At the micro level, the microstructure, hydration products and pore structure of concrete surface were analyzed by scanning electron microscopy (SEM), comprehensive thermal analysis (TG-DSC) and mercury intrusion porosimetry (MIP), respectively. The effect of carbonation on surface strength was also investigated. The results showed that the concrete surface hardness layer grew rapidly at early stage and then stabilized at last with ongoing curing age; the rebound value and compressive strength of concrete with slag were higher than those of concrete with the same content of fly ash. In addition, the strength curve obtained by the least square method can satisfy the local standard requirements with an average relative error of 8.9％ and a relative standard deviation of 11.3％. When the carbonation depth was 6 mm, the compressive strength calculated by national uniform strength curve was 25 PMa higher than that by high performance concrete.