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The title compound [Cu(bix)2(NO3)2?H2O]n 1 (bix =1,4-bis(imidazole-1-ylme-thyl) benzene) has been synthesized by hydrothermal method. Its crystal structure is of monoclinic, space group P1 with a = 8.3075(13), b = 9.4725(13), c = 10.0192(13) ?, α = 91.088(4), β = 104.063(6), γ = 101.88(1), V = 746.5(3) ?3, Z = 1, C28H30N10O7Cu1, Mr = 682.16, Dc = 1.518 g/cm3, μ = 0.796 mm─1, F(000) = 353, the final R = 0.0535 and wR = 0.0996 for 2921 observed reflections with I > 2σ(I). Each bix ligand binds two Cu(II) ions to form a 2-D(4,4) square grid layer, which is connected by hydrogen bonds showing large channels occupied by solvated water molecules and nitrate anions.
The title compound [Cu (bix) 2 (NO3) 2 · H2O] n1 (bix = 1,4-bis (imidazole- 1-ylme-thyl) benzene) has been synthesized by hydrothermal method. Its crystal structure is of monoclinic , space group P1 with a = 8.3075 (13), b = 9.4725 (13), c = 10.0192 (13) ?,? = 91.088 (4),? = 104.063 (6),? = 101.88 746.5 (3)? 3, Z = 1, C28H30N10O7Cu1, Mr = 682.16, Dc = 1.518 g / cm3, μ = 0.796 mm- 1, F (000) = 353, the final R = 0.0535 and wR = 0.0996 for 2921 observed reflections with I> 2σ (I). Each bix ligand binds two Cu (II) ions to form a 2-D (4,4) square grid layer, which is connected by hydrogen bonds showing large channels occupied by solvated water molecules and nitrate anions.