A novel benzoxazine-based phenolic resin containing furan groups(PFB) was synthesized via simple two-step reactions and the structure of PFB was confirmed by FTIR and ~1H NMR spectra.Differential scanning calorimetry(DSC) showed that the polybenzoxazine cured from PFB had good heat resistance and lower polymerization temperature compared with that of benzoxazine-based phenolic resins. A novel benzoxazine-based phenolic resin containing furan groups (PFB) was synthesized via simple two-step reactions and the structure of PFB was confirmed by FTIR and ~ 1H NMR spectra. Differential scanning calorimetry (DSC) showed that the polybenzoxazine cured from PFB had good heat resistance and lower polymerization temperature compared with that of benzoxazine-based phenolic resins.