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11种新的具分子内氮硼配位键的不对称二芳基硼酸芳氮杂环衍生物已由(m-氯苯基)苯基硼酸、(p-氯苯基)(p-甲苯基)硼酸和(p-氟苯基)(o-甲氧基苯基)硼酸分别与α-吡啶甲酸、喹哪啶酸以及8-羟基喹啉、8-羟基喹哪啶、5,7-二溴-8-羟基喹啉反应制得,它们的组成与结构由元素分析和红外光谱证实。
Eleven new kinds of asymmetric diarylboronic acid aromatic nitrogen derivatives with intramolecular boron nitride coordination bonds have been synthesized from (m-chlorophenyl) phenylboronic acid, (p-chlorophenyl) (p-tolyl ) Boronic acid and (p-fluorophenyl) (o-methoxyphenyl) boronic acid with α-picolinic acid, quinaldic acid and 8-hydroxyquinoline, Bromo-8-hydroxyquinoline prepared by the reaction, their composition and structure confirmed by elemental analysis and infrared spectroscopy.