引言由于硼氢化合物价鍵结构的特殊性及其各种潜在应用的可能性,在理论及应用方面都受到极为广泛的注意。在理论方面,三中心键及化学结构的拓扑理论研究都有了很大的发展。在应用方面,作为高能燃料的考虑曾脍炙一时,而近年来,应用硼氢化合物作为新材料的探索又甚嚣尘上。但是,硼氢化合物对于热、潮及各种化学反应的极端敏感性,却往往给研究工作带 INTRODUCTION Due to the particularity of the valence bond structure of borohydride and the potential for its various potential applications, both the theory and the application have received a great deal of attention. In theory, the research on topological theory of three-center bond and chemical structure have been greatly developed. In the field of application, the consideration as a high-energy fuel has been on the rise for a long time. In recent years, however, the exploration of using boron hydride as a new material has come a long way. However, extreme sensitivity of borohydride to heat, tide and various chemical reactions, but often to the research work with