A general and efficient Lewis acid catalysed Mukaiyama-aldol reaction of difluoroenoxysilanes and ke

来源 :科学通报：英文版 | 被引量 : 0次 | 上传用户：xuyixinsiboy

【摘要】

：

We report a general and highly efficient Mukaiyama-aldol reaction of ketones and difluoroenoxysilanes.While the reaction of aryl ketones worked efficiently in t

【作者】

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Fu-Min Liao Xiao-Tong Gao Xiao

【机构】

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ShanghaiKeyLaboratoryofGreenChemistryandChemicalProcesses,StateKeyLaboratoryofElemento-organicChemis

【出处】

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科学通报：英文版

【发表日期】

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2017年22期

【基金项目】

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AcknowledgmentsThis work was supported by the National Basic Research Program of China （2015CB856600） and the National Natural Science Foundation of China （21472049）.

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We report a general and highly efficient Mukaiyama-aldol reaction of ketones and difluoroenoxysilanes.While the reaction of aryl ketones worked efficiently in the presence of Bi(OTf)_3, that of aliphatic ketones required the use of Sc(OTf_)3. In addition,

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A general and efficient Lewis acid catalysed Mukaiyama-aldol reaction of difluoroenoxysilanes and ke

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