众所周知,甲醇羰基化反应能够被液相中的钴、镍、铑络合物有效地催化,并生成醋酸和醋酸甲酯。最近,本文作者曾报道过,该反应也可以用载在活性炭上的镍催化剂。在中等压力条件下和大约250℃的温度下进行。对所有这些催化剂来说,都存在有 It is well-known that methanol carbonylation can be effectively catalyzed by cobalt, nickel and rhodium complexes in the liquid phase to produce acetic acid and methyl acetate. Recently, the authors of this paper have reported that this reaction can also be performed on a nickel catalyst supported on activated carbon. Under moderate pressure and at a temperature of about 250 ° C. For all of these catalysts, there are