【摘 要】
：
The enthalpies of mixing of L-arginine with 2,2,2-trifluoroethanol and their respective enthalpies of dilution in aqueous solutions at 298.15,303.15 and 310.15
【机 构】
：
Department of Chemistry and Chemical Engineering,Key Laboratory of Colloid and Interface Chemistry
论文部分内容阅读
The enthalpies of mixing of L-arginine with 2,2,2-trifluoroethanol and their respective enthalpies of dilution in aqueous solutions at 298.15,303.15 and 310.15 K were determined as a function of the mole fraction by flow microcalorimetric measurement.These experimental results were analyzed to obtain heterotactic enthalpic interaction coefficients(hxy,hxxy,hxyy)according to the McMillan-Mayer theory.The hxy coefficients between L-arginine molecule studied and 2,2,2-trifluoroethanol molecule in aqueous solutions at 298.15,303.15 and 310.15 K were found to be all negative.The results were discussed in terms of solute-solute interaction and solute-solvent interaction.
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