【摘 要】
:
A novel pyridinium salt, 2,4-bis[p-(N,N-dimethylamino)styryl]-N-methyl pyridinium iodide (BMSPI) was syn-thesized and characterized by TG, 1H NMR spectroscopy a
【机 构】
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Department of Chemistry, Anhui University,Department of Chemistry, Anhui University,Department of Ch
【出 处】
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Chinese Journal of Chemistry
论文部分内容阅读
A novel pyridinium salt, 2,4-bis[p-(N,N-dimethylamino)styryl]-N-methyl pyridinium iodide (BMSPI) was syn-thesized and characterized by TG, 1H NMR spectroscopy and elemental analysis, and the reaction process was studied by using ES-MS. When BMSPI was pumped by a pulsed 1064 nm, 50 ps laser beam, it manifests highly ef-ficient TPA (Two-Photon Absorption) and up-conversion superradiance. The up-conversion efficiency was 6.0% at the pump energy of 4—6 mJ and the lifetime of two-photon fluorescence was measured as 59 ps.
A novel pyridinium salt, syn-thesized and characterized by TG, 1H NMR spectroscopy and elemental analysis, and the reaction process was studied by using ES-MS. The up-conversion efficiency was 6.0 when BMSPI was pumped by a pulsed 1064 nm, 50 ps laser beam, it manifests highly ef-ficient TPA (Two-Photon Absorption) % at the pump energy of 4-6 mJ and the lifetime of two-photon fluorescence was measured as 59 ps.
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