Synthesis, Characterization and Two-Photon Absorption Properties of a Novel Pyridinium Salt

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:jie_169
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A novel pyridinium salt, 2,4-bis[p-(N,N-dimethylamino)styryl]-N-methyl pyridinium iodide (BMSPI) was syn-thesized and characterized by TG, 1H NMR spectroscopy and elemental analysis, and the reaction process was studied by using ES-MS. When BMSPI was pumped by a pulsed 1064 nm, 50 ps laser beam, it manifests highly ef-ficient TPA (Two-Photon Absorption) and up-conversion superradiance. The up-conversion efficiency was 6.0% at the pump energy of 4—6 mJ and the lifetime of two-photon fluorescence was measured as 59 ps. A novel pyridinium salt, syn-thesized and characterized by TG, 1H NMR spectroscopy and elemental analysis, and the reaction process was studied by using ES-MS. The up-conversion efficiency was 6.0 when BMSPI was pumped by a pulsed 1064 nm, 50 ps laser beam, it manifests highly ef-ficient TPA (Two-Photon Absorption) % at the pump energy of 4-6 mJ and the lifetime of two-photon fluorescence was measured as 59 ps.
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