【摘 要】
：
The oxygenation constants and thermodynamic parameter (△H°, △S°) of a series of novel Co (Ⅱ) complexes with phenol ether bridged dihydroxamic acids CoL1-Co
【机 构】
：
College of Environmental and Biological Engineering,Department of Chemistry
论文部分内容阅读
The oxygenation constants and thermodynamic parameter (△H°, △S°) of a series of novel Co (Ⅱ) complexes with phenol ether bridged dihydroxamic acids CoL1-CoL6 were measured,their catalytic performance in oxidation of p-xylene to p-toluic acid (PTA) were examined. The modulation of O2-binding capabilities and catalytic oxidation activities by X (X = Cl, OCH3) and Y(Y = H, CH3, Cl) groups bonded to the aromatic rings of the Co (Ⅱ) complexes were investigated.
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