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以saloph为配体 ,醋酸碘苯 [PhI(OAc) 2 ]为氧源 ,考察了Mn等不同中心金属离子的配合物和不同溶剂对α 苯乙醇催化氧化反应的影响 ,同时又考察了不同取代基的水杨醛制备的配体所形成的锰配合物 2a～ 2g的催化氧化性能和不同底物在优化条件下的反应情况 .结果表明 ,锰配合物 2e在乙腈溶剂中催化性能最佳 .
Using saloph as ligand and iodine acetate [PhI (OAc) 2] as the oxygen source, the effects of different central metal ion complexes such as Mn and different solvents on the catalytic oxidation of α-phenylethanol were investigated. At the same time, The catalytic oxidation performance of 2a ~ 2g manganese complexes formed by the ligands prepared from salicylaldehyde and the reaction conditions of different substrates under optimized conditions show that manganese complexes 2e have the best catalytic performance in acetonitrile solvent.