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以亚戊基双(4'-苯并15-冠-5)为中性载体,制得对K ̄+、具有相近响应的PVC膜离子选择性电极。Nernst线性响应范围1×10 ̄(-1)~8×10 ̄(-5)mol/L;响应斜率为53mV/PM;对Li ̄+、Na ̄+、Ca ̄(2+)、Mg ̄(2+)、Ba ̄(2+)的选择性系数分别为6×10 ̄(-5),5×10 ̄(-3),3×10 ̄(-4),4×10 ̄(-4),8×10 ̄(-4)。用本电极可快速测出土壤肥料中速效氮、钾的含量。
With pentylene bis (4’-benzo-15-crown-5) as a neutral carrier, to K ~ +, has similar response PVC membrane ion selective electrode. The linear response range of Nernst is 1 × 10 ~ (-1) ~ 8 × 10 ~ (-5) mol / L, the response slope is 53mV / PM, and the response of Li ~ +, Na ~ +, Ca ~ (2 +), Mg ~ The selectivity coefficients of Ba 2+ were 6 × 10 -5, 5 × 10 -3, 3 × 10 -4, 4 × 10 -4, 8 × 10 ~ (-4). This electrode can be quickly measured soil available fertilizer nitrogen, potassium content.